Alternate identifier:
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Related identifier:
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Creator/Author:
Seitz, Tobias https://orcid.org/0009-0003-4039-3953 [RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1a, 52074 Aachen, Germany]

Walbeck, Marcel [RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1a, 52074 Aachen, Germany]

Hoffmann, Alexander https://orcid.org/0000-0002-9647-8839 [RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1a, 52074 Aachen, Germany]

Herres-Pawlis, Sonja https://orcid.org/0000-0002-4354-4353 [RWTH Aachen University, Institute of Inorganic Chemistry, Landoltweg 1a, 52074 Aachen, Germany]
Contributors:
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Title:
Experimental Data to the publication ""Electron transfer kinetics of a series of copper complexes with tripodal tetradentate guanidine quinolinyl ligands"
Additional titles:
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Description:
(Abstract) Optimized coordinates otained from DFT calculations, Cyclic Voltammetry measurements and results of stopped-flow UV/Vis spectroscic measurements were deposited.
Keywords:
DFT optimized coordinates
Stopped-flow UV/Vis spectroscopic measurements
cyclic voltammetry
Related information:
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Language:
English
Publishers:
RWTH Aachen University
Production year:
Subject areas:
Chemistry
Resource type:
(Dataset) Optimized coordinates otained from DFT calculations, Cyclic Voltammetry measurements and stopped-flow UV/Vis spectroscic data
Data source:
(Instrument) The stopped-flow measurements were performed with a HI-TECH Scientific SF-61SX2 device with a diode array detector. The optical light path for transmission of the quartz glass cuvette was 10 mm.
(Instrument) The measurements were performed with a METROHM AUTOLAB PGSTAT 101 potentiostat using a three-electrode arrangement with a Pt disc working electrode (1 mm diameter), a Pt wire as counter electrode and an Ag/AgCl (in saturated ethanolic LiCl) reference electrode. The measurements were performed in MeCN and 100 mmol/L NBu4PF6 with a sample concentration of 1 mmol/L at room temperature. Ferrocene was added as an internal standard after the measurements of the sample and all potentials are referenced relative to the Fc/Fc+ potential. Cyclic voltammograms were measured with 200 mV·s–1, 100 mV·s–1, 50 mV·s–1 and 20 mV·s–1.
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Gaussian 16 - Revision B01
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Chemcraft - 1.8
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notepad - 7.8.1
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Kinetic Studio - 4.0.8.18533
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Software:
OriginPro 2021b - 9.8.5.212
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Software:
NOVA from Metrohm Autolab - 2.1.5 (Build 7691)
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Publication year:
Rights holders:
RWTH Aachen University
Funding:
Deutsche Forschungsgemeinschaft - (Kontrolle des entatischen Zustands durch die gezielte optische Anregung der Ligandensphäre) 413524714
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iac_Radar_Produktion
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Archiving date:
2024-11-16
Archive size:
548.5 MB
Archive creator:
iac_Radar_Produktion
Archive checksum:
e6eae8992431c213d5edc0df1d2eb740 (MD5)
Embargo period:
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